A Titanium(III)‐Catalyzed Reductive Umpolung Reaction for the Synthesis of 1,1‐Disubstituted Tetrahydroisoquinolines.

Hieu-Trinh Luu,Stefan Wiesler,Georg Frey,Jan Streuff

ChemInform（2015）

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摘要

A reductive C-1 acylation of 3,4-dihydroisoquinolines is developed that gives selective access to 1,1-disubstituted tetrahydroisoquinolines via a Ti(III)-catalyzed umpolung process.

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关键词

reductive umpolung reaction,synthesis,cheminform abstract

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