Catalytic Enantioselective Synthesis of Planar‐Chiral Cyclic Amides Based on a Pd‐Catalyzed Asymmetric Allylic Substitution Reaction.
ChemInform(2015)
摘要
The highly enantioselective synthesis of planar-chiral nine-membered cyclic amides was achieved by the Pd-catalyzed asymmetric allylic cyclization of achiral linear precursors in the presence of a catalytic amount of chiral ligand.
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