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Asymmetric Total Synthesis of (‐)‐trans‐Blechnic Acid via Rhodium(II)‐Catalyzed C—H Insertion and Palladium(II)‐Catalyzed C—H Olefination Reactions.

Motoki Ito,Ryosuke Namie,Janagiraman Krishnamurthi,Hitomi Miyamae,Koji Takeda,Hisanori Nambu,Shunichi Hashimoto

ChemInform（2014）

Cited 7|Views1
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Abstract
(-)-trans-blechnic acid (I) has an uncommon 2,3-cis-stereochemistry and belongs to the dihydrobenzofuran neolignans, which exhibit several biological activities.
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Key words
asymmetric total synthesis,total synthesis,palladiumii-catalyzed,reactions,trans-blechnic
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