Stereoselective Reaction of 2-Carboxythioesters-1,3-dithiane with Nitroalkenes: An Organocatalytic Strategy for the Asymmetric Addition of a Glyoxylate Anion Equivalent.

Elisabetta Massolo,Maurizio Benaglia,Andrea Genoni,Rita Annunziata,Giuseppe Celentano,Nicoletta Gaggero

ChemInform（2015）

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摘要

The enantioselective organocatalyzed conjugate addition of a newly activated thioester acting as an acyl anion mimic is presented using a chiral bifunctional catalyst to control the stereochemistry.

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关键词

glyoxylate anion equivalent,stereoselective reaction,nitroalkenes,organocatalytic strategy,asymmetric addition

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