Palladium‐Catalyzed Double Substitution of 3‐Aryl‐2‐fluoroallyl Acetates with Phenols via C—F Bond Activation.

Eito Nomada,Hirotaka Watanabe,Mitsuaki Yamamoto,Takumi Udagawa,Biao Zhou,Akiko Kobayashi,Maki Minakawa,Motoi Kawatsura

ChemInform（2015）

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摘要

The double substitution of 3-aryl-2-fluoroallyl acetates with phenols has been accomplished; the Pd(PPh 3 ) 4 catalyst system has effectively catalyzed the reaction to afford the doubly substituted product via carbon–fluorine bond activation.

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