Synthesis of β‐Ketonitriles, α,β‐Alkynones and Biscabinols from Esters Using tert‐Butoxide‐Assisted C(=O) (i.e., Acyl—C) Coupling under Ambient Conditions.
ChemInform（2014）
Abstract
A rapid, simple, and mild method for the metal‐free coupling reaction of esters with benzyl cyanides or acetylenes to give the title compounds is developed.
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Key words
biscabinols,synthesis,esters,tert-butoxide-assisted
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