M2+ and Ln3+-Catalyzed Synthesis of a [1,2,4]Triazine Core via Intramolecular C—H/N—H Functionalization and C—N Bond Formation (M: Mn, Zn, Cd; Ln: Dy, Tb).

Wen-Bin Chen,Zhi-Xin Li,Xin-Wei Yu,Meng Yang,Yan-Xuan Qiu,Wen Dong

ChemInform（2015）

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摘要

A new approach to the direct construction of the 1,2,4-triazine core starting from eight azo-conjugated aromatic compounds via transition or lanthanide metal-catalyzed cross-dehydrogenative coupling reactions under hydrothermal conditions is reported.

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