Single-Electron Transmetalation: Synthesis of 1,1-Diaryl-2,2,2-trifluoroethanes by Photoredox/Nickel Dual Catalytic Cross-Coupling.

DaWeon Ryu,David N. Primer,John C. Tellis,Gary A. Molander

ChemInform（2016）

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摘要

To circumvent conventional Suzuki-coupling protocols, a novel method for the cross-coupling of benzylic α-trifluoromethylated alkylboron reagents with (hetero)aryl bromides is developed.

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关键词

cheminform abstract,photoredox/nickel,synthesis,single-electron,cross-coupling

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