Electrical and Mechanical Properties of Intrinsically Flexible and Stretchable PEDOT Polymers for Thermotherapy
ACS APPLIED POLYMER MATERIALS(2021)
摘要
For wearable applications such as electronic skin and biosensors, stretchable conductors are required (similar to 30% strain to follow the skin extension). Owing to its high conductivity, good flexibility, low cost, and ease of processing, poly(3,4-ethyl-enedioxythiophene) (PEDOT) appears as a promising candidate. However, destructive cracks come out above 10% strain in the case of PEDOT:PSS, the most common form of PEDOT. Different strategies have already been investigated to solve this problem, including the design of specific structures or the addition of plasticizers. This article presents a different approach to obtain highly conductive and stretchable PEDOT materials based on doping with small counteranions. We indeed demonstrate the intrinsic stretchability (up to 30% strain) of thin films (35 nm) of PEDOT-based materials with small counterions. Both thin-PEDOT:OTf (triflate counter-ion) and thin-PEDOT:Sulf (sulfate counter-ion) films remain structurally resilient up to 25-30% strain, and their electrical conductivity remains remarkably stable over more than 100 cycles. Under limited strain (<30%), polarized UV-vis-NIR measurements (parallel and perpendicular to the stretching direction) show that the conductivity of the material is improved by chain alignment in the stretching direction. As a proof of concept, a thermotherapy patch is presented. It shows a fine temperature control (stability around 40 degrees C at 9 V bias) and a uniform heating across the surface.
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关键词
conducting polymers,intrinsic stretchability,thermotherapy,polarized UV-vis-NIR spectroscopy,transparent film heater
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