Recent developments in metal-doped SBA-15 catalysts for heterogeneous catalysis and sustainable chemistry

Canadian Journal of Chemistry(2022)

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摘要
The development of new advanced sustainable materials for heterogeneous catalysis requires control of the structural parameters of the active sites. Mesoporous silica, especially SBA-15, has some unique and important features such as highly ordered mesopores, greater hydrothermal stability, greater wall thickness, large surface area, and adjustable pore volume. All these properties render it a promising material for catalysis, adsorption, supporting materials, biomedical applications, and environmental remediation. However, pure SBA-15 lacks acidic characteristics, which hinders its catalytic activity. Therefore, the functionalized SBA-15 improves the catalytic activity for versatile applications. Thus, in this study, we attempted to summarize the synthesis procedures, various functionalization processes, and application of metal-modified SBA-15 in organic synthesis, fine chemical synthesis, photocatalysis, and decontamination of water. Furthermore, the physicochemical properties, sustainability, and efficacy are discussed in detail for future reference and scope of studies.
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关键词
nanocomposite, metal-substituted SBA-15, organic transformation, environmental application
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