Determination of the time-dependent change in the vapor concentration of 2,4,6-trinitrotoluene during the sublimation of its traces from the glass surface

The results of the measurements of 2,4,6-trinitrotoluene ( TNT ) vapor concentration over its trace amounts, called thin films, on the glass surface with a concentration of 100 ng/cm 2 in a square area with a side of 1 cm over time are presented. The trace amounts of TNT on the glass were formed by applying a solution of TNT in the acetonitrile diluted with the chemically pure acetone, followed by the evaporation of the solvents. In order to measure the TNT vapor concentration, an EKHO-V-IDTS portable multibacillary gas-chromatograph with preliminary TNT vapor concentration was used. A sampling of the TNT vapor above the object was carried out with a remote vortex sampler. The vapor sample was taken from a distance of 2 cm from the glass surface. The concentration in the mode of the complete capture of TNT vapors was carried out to the stainless-steel wire mesh. The vapor concentration was determined from the chromatographic peak amplitude. It was found that the concentration of vapor over the examined surface with an area of 1 cm 2 decreases from 10 -13 to 10 -14 g/cm 3 within 2.6 ± 0.3 hours. TNT vapor concentration value of 10 -14 g/cm 3 corresponds to the threshold concentration of TNT vapor for the modern detectors. Based on the assumption that the vapor concentration is proportional to the amount of the TNT mass on the surface for the considered trace amounts of TNT, it was estimated that the initial surface concentration of trinitrotoluene of 100 ng/cm 2 on the glass surface decreases to 12 ng/cm 2 within 2.6 ± 0.3 hours due to sublimation into an open half-space. It was shown that the use of vortex sampling of vapor intensifies the sublimation of TNT from the glass surface. Key words: films of 2,4,6-trinitrotoluene, sublimation of films, sublimation rate, trace concentrations of TNT vapor DOI: http://dx.doi.org/10.15826/analitika.2021.25.3.003 M.I. Tivileva 1 , V.M. Gruznov 2,3,4 , M.N. Baldin 2 , A.V. Kikhtenko 2 , I.I. Naumenko 2 1 Siberian Branch of the Federal Government Institution, Scientific and Production Association, Special Equipment and Telecoms of the Ministry of Internal Affairs, Kutateladze str. 3, Novosibirsk, 630055, Russian Federation 2 Trophimuk Institute of Petroleum Geology and Geophysics SB RAS, Koptyug ave. 3, Novosibirsk, 630090, Russian Federation 3 Novosibirsk State University, Pirogova str. 1, Novosibirsk, 630090, Russian Federation 4 Novosibirsk State Technical University, Karl Marx ave. 20, Novosibirsk, 630073, Russian Federation