Insight into the structure–property relationship of UO₂ nanoparticles

Evgeny Gerber,Anna Yu. Romanchuk,Stephan Weiss,Stephen Bauters,Bianca Schacherl,Tonya Vitova,René Hübner,Salim Shams Aldin Azzam,Dirk Detollenaere,Dipanjan Banerjee,Sergei M. Butorin,Stepan N. Kalmykov,Kristina O. Kvashnina

Inorganic Chemistry Frontiers（2021）

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摘要

We show that the structural and electronic properties of UO2 NPs (2–3 nm) are similar to those of bulk UO2 under inert conditions, with U(iv) as the dominating oxidation state, though NPs oxidize with time and under the X-ray beam.

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Insight into the structure–property relationship of UO2 nanoparticles

Insight into the structure–property relationship of UO₂ nanoparticles