Ruthenium(ii)-supported phosphovanadomolybdates [Ru(dmso)₃PMo₆V₃O₃₂]⁶⁻ and [Ru(PMo₆V₃O₃₂)₂]¹⁴⁻, and their use as heterogeneous catalysts for oxidation of alcohols

Hao-Yu Shi,Wen-Yan Zhou,Xiao-Ming Song,Ai-Quan Jia,Hua-Tian Shi,Qian-Feng Zhang

New Journal of Chemistry（2021）

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摘要

Two stable ruthenium(ii)-substituted phosphovanadomolybdates [RuII(dmso)3PMoVI6VV3O32]6− and [RuII(PMoVI6VV3O32)2]14− are synthesized. They could catalyze oxidation of alcohols with good conversion and selectivity.

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Ruthenium(ii)-supported phosphovanadomolybdates [Ru(dmso)3PMo6V3O32]6− and [Ru(PMo6V3O32)2]14−, and their use as heterogeneous catalysts for oxidation of alcohols

Ruthenium(ii)-supported phosphovanadomolybdates [Ru(dmso)₃PMo₆V₃O₃₂]⁶⁻ and [Ru(PMo₆V₃O₃₂)₂]¹⁴⁻, and their use as heterogeneous catalysts for oxidation of alcohols