Disorder in Ho₂Ti_2−xZr_xO₇: pyrochlore to defect fluorite solid solution series

Devon L. Drey,Eric C. O'Quinn,Tamilarasan Subramani,Kristina Lilova,Gianguido Baldinozzi,Igor M. Gussev,Antonio F. Fuentes,Joerg C. Neuefeind,Michelle Everett,David Sprouster,Alexandra Navrotsky,Rodney C. Ewing,Maik Lang

RSC Advances（2020）

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摘要

Combined neutron and X-ray total scattering with calorimetric measurements of the solid solution series Ho2Ti2−xZrxO7 reveals a complex order–disorder transition across short, intermediate, and long length scales induced by chemical substitution.

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Disorder in Ho2Ti2−xZrxO7: pyrochlore to defect fluorite solid solution series

Disorder in Ho₂Ti_2−xZr_xO₇: pyrochlore to defect fluorite solid solution series