Interstellar polycyclic aromatic hydrocarbons: Spectroscopy, photofragmentation and photoproducts

AbstractUbiquitous strong mid-infrared emission bands are observed towards many objects and are attributed to interstellar Polycyclic Aromatic Hydrocarbons (PAHs). PAHs are ionized, or even dissociate, when exposed to strong interstellar radiation fields. By means of ion trap mass spectrometry, light-induced dissociation patterns of PAH cations are measured and the mid-infrared spectroscopic signatures of the parent ion and its dissociation products are characterized. These results are then combined with density functional theory (DFT) calculations to obtain insight into the dissociation characteristics of interstellar PAHs at a molecular level.