[Re(η⁶-arene)₂]⁺ as a highly stable ferrocene-like scaffold for ligands and complexes

Daniel Hernández-Valdés, Frédéric Avignon,Peter Müller,Giuseppe Meola,Benjamin Probst,Thomas Fox,Bernhard Spingler,Roger Alberto

Dalton Transactions（2020）

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摘要

Sandwich complexes [Re(η6-C6H6)2]+ are versatile scaffolds for conjugating a variety of ligands, as in ferrocene. The high stability of a so-prepared Re/Co system under light irradiation is exemplified with photocatalysis for proton reduction.

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[Re(η6-arene)2]+ as a highly stable ferrocene-like scaffold for ligands and complexes

[Re(η⁶-arene)₂]⁺ as a highly stable ferrocene-like scaffold for ligands and complexes