Noncovalent Close Contacts in Fluorinated Thiophene–Phenylene–Thiophene Conjugated Units: Understanding the Nature and Dominance of O···H versus S···F and O···F Interactions with Respect to the Control of Polymer Conformation

Tetiana Kharandiuk,Eman J. Hussien,Joseph Cameron,Romana Petrina,Neil J. Findlay,Roman Naumov,Wim T. Klooster,Simon J. Coles,Qianxiang Ai,Stephen Goodlett,Chad Risko,Peter J. Skabara

Chemistry of Materials（2019）

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Abstract

Using a simple π-conjugated trimer, EDOT–phenylene–EDOT (EDOT = 3,4-ethylenedioxythiophene), we evaluate the effect that fluorine substituents have upon changes in conformation, conjugation, and ox...

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Key words

thiophene–phenylene–thiophene conjugated units,fluorinated thiophene–phenylene–thiophene,polymer,noncovalent close contacts

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