Controlling magnetism of Au₁₃₃(TBBT)₅₂ nanoclusters at single electron level and implication for nonmetal to metal transition

Chemical Science（2019）

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摘要

The [Au133(SR)52]q nanocluster is discovered to possess one spin per particle when q = 0, but no unpaired electron when q = +1.

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Controlling magnetism of Au133(TBBT)52 nanoclusters at single electron level and implication for nonmetal to metal transition