Magnetic Properties of Hole-Doped Pyrochlore Iridate (Y<sub>1-</sub><i><sub>x</sub></i><sub>-</sub><i><sub>y</sub></i>Cu<i><sub>x</sub></i>Ca<i><sub>y</sub></i>)<sub>2</sub>Ir<sub>2</sub>O<sub>7</sub>

Materials Science Forum(2019)

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摘要
We report the results of studies on the electronic state of the hole-doped Y-based pyrochlore iridate, (Y1-x-yCuxCay)2Ir2O7. We carried out the resistivity, Muon Spin Relaxation (μSR), X-ray Photoemission Spectroscopy (XPS) measurements and Density Functional Theory (DFT) calculations on the non-doped (x=y=0) and doped (x=0.05, y=0.15) systems. We found in the non-doped system that the magnetic ordering of Ir spins which was accompanied by the metal-insulator transition (MIT) occurred at around 157 K and disappeared in the doped system in which MIT seems to disappear or smeared out. We suggest from the current study that a quantum critical point which shows a change in the electronic ground state from insulating to metallic to exist between those two systems.
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magnetic properties,hole-doped
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