Gram-scale synthesis of porphycenes through acid-catalyzed oxidative macrocyclizations of E/Z-mixed 5,6-diaryldipyrroethenes

Toshikazu Ono, Ning Xu,Daiki Koga,Toshihiro Ideo,Manabu Sugimoto,Yoshio Hisaeda

RSC Advances（2018）

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摘要

A set of novel porphycenes was synthesized on a gram-scale in high overall yields by optimization of macrocyclization of E/Z-mixed 5,6-diaryldipyrroethenes.

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