Transition metal-free direct dehydrogenative arylation of activated C(sp³)–H bonds: synthetic ambit and DFT reactivity predictions

Chemical Science（2018）

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摘要

A direct and general mono-arylation of activated C(sp3)–H bonds with nitroarenes under transition metal-free conditions has been developed.

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Transition metal-free direct dehydrogenative arylation of activated C(sp3)–H bonds: synthetic ambit and DFT reactivity predictions