Stereoselective Total Synthesis of (-)-6-epi-Hygrophorone B14and (-)-4-epi-Hygrophorone D14

ChemistrySelect(2018)

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Abstract
Abstract Total synthesis of (–)–6– epi – hygrophorones B 14 and (–)–4– epi –hygrophorone D 14 was achieved using stereoselective Grignard reaction, Bernet–Vasella protocol and Ring closing metathesis, starting from D–mannose.
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Key words
stereoselective total synthesis,total synthesis
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