Stereoselective aldol reactions using pseudo C₂ symmetric 1-benzyl-4-(trifluoromethyl)piperidine-2,6-dione

Yuta Inoue,Takahiro Hatayama,Tomoko Kawasaki-Takasuka,Tomohiro Agou,Toshio Kubota,Takashi Yamazaki

Chemical Communications（2018）

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摘要

Crossed aldol reactions of the CF3-containing pseudo C2 symmetric cyclic imide 3 were performed by way of the corresponding lithium and boron bisenolates to stereoselectively furnish the desired products 4.

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Stereoselective aldol reactions using pseudo C2 symmetric 1-benzyl-4-(trifluoromethyl)piperidine-2,6-dione

Stereoselective aldol reactions using pseudo C₂ symmetric 1-benzyl-4-(trifluoromethyl)piperidine-2,6-dione