Stereocontrolled Formal Synthesis of Platencin
European Journal of Organic Chemistry(2018)
摘要
A stereocontrolled formal synthesis of platencin was accomplished in 11 steps from a bromophenol derivative, with an overall yield of 13 %. The intermolecular Diels–Alder reaction of masked o ‐benzoquinone and an aldol condensation were the key steps in the construction of the tricyclic core of platencin.
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关键词
Polyketide Biosynthesis
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