Probing the factors that influence the conformation of a guanidinato ligand in [(η⁵-C₅Me₅)M(NN)X] (NN = chelating N,N′,N′′-tri(o-substituted aryl)guanidinate(1−); X = chloro, azido and triazolato)

Robin Kumar,Ram Kishan,Jisha Mary Thomas,Sivasankar Chinnappan,Natesan Thirupathi

New Journal of Chemistry（2018）

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摘要

The conformational difference illustrated is ascribed to a subtle repulsive interaction between the o-Cl substituent of two proximal aryl rings in the guanidinate ligand.

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Probing the factors that influence the conformation of a guanidinato ligand in [(η5-C5Me5)M(NN)X] (NN = chelating N,N′,N′′-tri(o-substituted aryl)guanidinate(1−); X = chloro, azido and triazolato)

Probing the factors that influence the conformation of a guanidinato ligand in [(η⁵-C₅Me₅)M(NN)X] (NN = chelating N,N′,N′′-tri(o-substituted aryl)guanidinate(1−); X = chloro, azido and triazolato)