Construction of lanthanide single-molecule magnets with the “magnetic motif” [Dy(MQ)4]

Inorganic Chemistry Frontiers(2017)

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Abstract
[Dy2(MQ)4(NO3)3]+ is SMM-silent (SMM = single-molecule magnet) owing to the unfavourable magnetic interactions. Introducing an additional “magnetic motif” [Dy(MQ)4]− to diminish such interactions gave a trinuclear [Dy3(MQ)8(NO3)], which behaves as an SMM.
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Key words
magnetic motif”,single-molecule
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