Na₆Si₃S₈O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si₃S₈O]⁶⁻units without S–O bonds

Dalton Trans.（2017）

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摘要

A new sulfide silicate – Na6Si3S8O – featuring novel tri-polymerized [Si3S8O]6−units without common S–O bonds has been verified as a promising birefringent material.

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Na6Si3S8O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si3S8O]6−units without S–O bonds

Na₆Si₃S₈O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si₃S₈O]⁶⁻units without S–O bonds