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Synthesis of a labile sulfur-centred ligand, [S(H)C(PPh2S)2]−: structural diversity in lithium(i), zinc(ii) and nickel(ii) complexes

Ramalingam Thirumoorthi,Tristram Chivers,Susanna Häggman,Akseli Mansikkamäki,Ian S. Morgan,Heikki M. Tuononen,Manu Lahtinen,Jari Konu

Dalton Transactions（2016）

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Abstract
Structural isomerism: formation of a labile tridentate sulfur-ligand led to the isolation of the first examples of Ohand SP Ni(ii) isomers of the same ligand in [Ni{S(H)C(PPh2S)2}2] and their fluxional behaviour is examined.
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