α-Phosphino Amino Acids: Synthesis, Structure, and Reactivity

Joachim Heinicke,Joanna Lach,Kaleswara R. Basvani,Normen Peulecke,Peter G. Jones,Martin Köckerling

Phosphorus, Sulfur, and Silicon and the Related Elements（2011）

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摘要

Abstract One-pot three-component reactions of secondary or primary phosphines and primary amines with glyoxylic acid provide a wide variety of acyclic or cyclic phosphinoglycines, in the case of some chiral amines with high diastereoselectivity. The structure, hydrolysis, oxidation, coordination at M(CO)5 (M = Cr, Mo, W), and use in nickel-catalyzed ethylene oligomerization were studied.

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