α-Phosphino Amino Acids: Synthesis, Structure, and Reactivity of Phosphaprolines
Phosphorus, Sulfur, and Silicon and the Related Elements(2011)
Abstract
Abstract Linear phosphinoglycines proved sensitive to hydrolysis. Routes to heterocyclic α-phosphino amino acids were therefore investigated. The more stable phenylphosphaproline and some N- or C2-substituted derivatives thereof were synthesized from 2-phenylphosphino-ethylamines and α-ketocarboxylic acids. With Ni(COD)2 they form greenish yellow complex solutions that in the presence of NaH generate ethylene oligomerization catalysts.
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Key words
phosphaprolines,amino acids
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