Design of a Metal-Oxide Solid Solution for Sub-ppm H-2 Detection

Hydrogen is largely adopted in industrial processes and is one of the leading options for storing renewable energy. Due to its high explosivity, detection of H-2 has become essential for safety in industries, storage, and transportation. This work aims to design a sensing film for high-sensitivity H-2 detection. Chemo-resistive gas sensors have extensively been studied for H-2 monitoring due to their good sensitivity and low cost. However, further research and development are still needed for a reliable H-2 detection at sub-ppm concentrations. Metal-oxide solid solutions represent a valuable approach for tuning the sensing properties by modifying their composition, morphology, and structure. The work started from a solid solution of Sn and Ti oxides, which is known to exhibit high sensitivity toward H-2. Such a solid solution was empowered by the addition of Nb, which-according to earlier studies on titania films-was expected to inhibit grain growth at high temperatures, to reduce the film resistance and to impact the sensor selectivity and sensitivity. Powders were synthesized through the sol-gel technique by keeping the Sn-Ti ratio constant at the optimal value for H-2 detection with different Nb concentrations (1.5-5 atom %). Such solid solutions were thermally treated at 650 and 850 degrees C. The sensor based on the solid solution calcined at 650 degrees C and with the lowest content of Nb exhibited an extremely high sensitivity toward H-2, paving the way for H-2 ppb detection. For comparison, the response to 50 ppm of H-2 was increased 6 times vs SnO2 and twice that of (Sn,Ti)xO(2).