Flory-Huggins VOC Photonics Sensor Made of Cellulose Derivatives

ACS APPLIED MATERIALS & INTERFACES(2022)

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Abstract
As a widespread air pollutant, volatile organic compounds (VOCs) are harmful to the human body's skin, nervous system, and respiratory system. Low-cost, extensive, and continuous detection of VOCs is of great significance to human health. We infiltrated and coated cellulose acetate on the inverse opal photonic crystal skeleton of methylcellulose-polyvinyl alcohol-graphene oxide to construct a degradable, high-toughness cellulose VOC sensor. Cellulose acetate enhances the response to VOCs and achieves a highly selective response to acetone vapor due to the smaller Flory-Huggins parameter with acetone. This work proposes a general, simple, easy-to-use, and highly selective photonic crystal VOC sensor development strategy. Calculated from the Flory-Huggins solution theory, a suitable polymer was selected to modify the inverse opal photonic crystal framework and achieve high selectivity detection.
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Key words
3D photonic crystal, sensors, vapor detection, Flory-Huggins, cellulose derivatives
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