In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol
NANOMATERIALS(2022)
摘要
Exploiting biomass to synthesise compounds that may replace fossil-based ones is of high interest in order to reduce dependence on non-renewable resources. 1,2-pentanediol and 1,5-pentanediol can be produced from furfural, furfuryl alcohol or tetrahydrofurfuryl alcohol following a metal catalysed hydrogenation/C-O cleavage procedure. Colloidal ruthenium nanoparticles stabilized with polyvinylpyrrolidone in situ modified with different organic compounds are able to produce 1,2-pentanediol directly from furfural in a 36% of selectivity at 125 degrees C under 20 bar of H-2 pressure.
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关键词
nanocatalysis, ruthenium, furfural, biomass, pentanediol
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