Ion exchange membrane optimized light-driven photoelectrochemical unit for efficiency simultaneous organic degradation and metal recovery from the mine wastewater

Resource recovery from wastewater is a promising and challenging topic. Herein, a well-designed ion exchange membrane optimized light-driven photoelectrochemical unit (MPECS) was constructed to reduce the effect of inorganic salt on the photoelectrochemical performance of the photoanode. TiO2/carbon dots/WO3 (TCDW) photoanode with the indirect Z-scheme heterojunction structure was successfully fabricated, achieving a strong light harvest performance (10.82%) and a high photocurrent density (5.39 mA/cm2). For the simulated solution (0.01 M phenol and 0.01 M CuSO4), the phenol degradation and Cu recovery efficiencies reached 99.67% and 62.20% in 60 min, respectively, and the corresponding photoelectric conversion efficiency (PECE) reached 4.64% in the TCDW/Pt-based MPECS. For the actual Cu-laden mine wastewater, over 98% of inorganic salt was removed. Compared to the traditional photoelectrochemical system (PECS), the COD removal and Cu recovery efficiencies were further improved by 23.77% and 49.41% in MPECS, respectively. The results exhibited a promising light-driven mine wastewater treatment technology.