Nanoporous germanium prepared by a mechanochemical reaction with enhanced lithium storage properties

The cost-effective and facile fabrication of nanostructured germanium for lithium-ion batteries (LIBs) remains a grand challenge. Herein, nanoporous Z-Ge was generated via a facile two-step mechanochemical-etching reaction with Mg2Ge and ZnCl2. The prepared nanoporous Ge nanoparticles, as the anode for Li-Ge half cells, showed superior LIB performance, in terms of a high capacity, good rate capability, and good long-term stability of 700 cycles. Significantly, the mechanochemical reaction was extended to produce other nanoporous Ge or Si materials such as A-Ge, Z-Si, and A-Si via the mechanochemical reaction between Mg2Ge and AlCl3, Mg2Si and ZnCl2, and Mg2Si and AlCl3.