High pressure synthesis and the valence state of vanadium ions for the novel transition metal pernitride, CuAl2-type VN2.

Shuto Asano,Ken Niwa,Takuya Sasaki,Nico Alexander Gaida,Masashi Hasegawa

DALTON TRANSACTIONS（2022）

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摘要

A novel transition metal pernitride, CuAl2-type VN2, has been synthesized at a pressure above 73.3 GPa. The bulk modulus has been determined to be K0 = 347(12) GPa. By hard X-ray absorption spectrum measurements of VN2, the valence state of transition metal ions in pernitrides has been for the first time experimentally reported.

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