Effect of active multi-walled carbon nanotubes (MWCNT) on the energy storage density of DI water for cool thermal storage system

The present research work aims to investigate the energy saving aspects in cool thermal energy storage system (CTES) by improving the thermophysical properties of deionized (DI) water. The influence of phase change enthalpy, specific heat, thermal conductivity, and cooling rate of the DI water for the dispersion of chemically functionalized multi-walled carbon nanotubes (f-MWCNT) is studied experimentally. The covalent functionalization method is used to modify the surface of the multi-walled carbon nanotubes (MWCNT) with the use of concentrated nitric acid. The nanofluid phase change materials (PCMs) in different mass concentrations (0.25%, 0.50%, and 0.75%) were prepared by dispersions of the f-MWCNT in DI water. The minimum reduction in enthalpy (4.01%) was recorded for the nano-PCM with 0.75% f-MWCNT as compared to the base PCM with 0.5% of sodium dodecyl benzene-sulfonate (10%). The thermal conductivity enhancement of 53.15% and 28.2% was recorded in both states for the nano-PCM (with 0.75%) at the temperature of − 10 °C and 5 °C respectively. Also, the enhancement of 30% and 23% in cooling rate is recorded for the dispersion of maximum concentration of f-MWCNT at the HTF temperatures of − 8 °C and − 6 °C, respectively. It is proven from the above findings that the dispersion of f-MWCNT reduces the subcooling and facilitates the running of the CTES system at a higher operating temperature.