Structurally Nontraditional Bipolar Hosts for RGB Phosphorescent OLEDs: Boosted by a "Butterfly-Shaped" Medium-Ring Acceptor
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION(2022)
摘要
The emitting layer based on a host-guest system plays a crucial role in organic light-emitting diodes (OLEDs). While emitters have witnessed rapid progress in structural diversity, hosts still rely heavily on traditional structures and are underdeveloped. Herein a "medium-ring" strategy has been put forward to design structurally nontraditional host molecules, which are not only rotatable enough to suppress close pi-pi stacking, thus reducing exciton annihilation, but also rigid enough to prevent excessive conformational flipping, thus inhibiting non-radiative decay. Accordingly, a brand-new type of bipolar hosts with a twisted "butterfly-shaped heptagonal acceptor (EtBP), which features an electron-deficient benzophenone fragment with a flexible ethylidene bridge, has been developed. With satisfactory morphological stability and well-balanced hole- and electron-transporting properties, the EtBP-based bipolar hosts enable high-performance RGB phosphorescent OLEDs with small efficiency roll-off, which are superior to those of acyclic benzophenone-based devices.
更多查看译文
关键词
Balanced Hole- and Electron-Transporting Properties, Bipolar Host, C-H, C-H Cross-Coupling, Medium-Ring Acceptor, Phosphorescent OLEDs
AI 理解论文
溯源树
样例
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要