AgNTf2‑Catalyzed Regioselective C–H Alkenylation of N,N-Dialkylanilines with Ynamides

The Journal of Organic Chemistry(2022)

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Abstract
Regioselective C–H alkenylation of N,N-dialkylanilines with ynamides was developed using AgNTf2 as a catalyst. This approach represents a facile hydroarylation of ynamides, allowing for the introduction of an alkenyl group exclusively at the para position of aniline derivatives. As a result, a series of 4-alkenyl N,N-dialkyl­anilines were synthesized with excellent regioselectivities.
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