Rapid Synthesis of Luotonin A Derivatives via Synergistic Visible-Light Photoredox and Acid Catalysis

Feng Wu,Wuheng Dong,Sijie Fan,Yao Yuan,Caiyun Liang, Aiyu Chen,Zuodong Yin,Zhaoguo Zhang

The Journal of Organic Chemistry（2022）

引用 4|浏览5

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摘要

The merging of visible-light photoredox and acid catalysis allowed for an intramolecular Povarov cycloaddition reaction using eosin Y as the photocatalyst and TsOH·H2O as the co-catalyst. A visible-light-promoted dehydrogenative cyclization protocol enabled the construction of Luotonin A derivatives with up to 97% yield.

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