An online technology for effectively monitoring inorganic condensable particulate matter emitted from industrial plants.

The concentration of condensable particulate matter (CPM) has gradually exceeded that of filterable particulate matter emitted from industrial plants equipped with advanced air pollution control systems. However, there is still no available online technology to measure CPM emissions. Based on the significant linear correlations (R2 > 0.87, p < 3 × 10-3) between the electrical conductivity (EC) values and ionic mass concentrations of the CPM solutions when the interference of H+ was excluded. We developed an online inorganic CPM monitoring system, including a cooling and condensation unit, pH and EC meters, a self-cleaning unit, and an automatic control unit. The CPM mass concentrations obtained by the developed online monitoring system agree well (mean bias 3.8-20.7%) with those obtained by the offline system according to USEPA Method 202 when used in parallel during real-world studies. Furthermore, individual ion mass concentrations of CPMs can even be retrieved separately with a time resolution of one hour when industrial plants are under steady operating conditions. The newly developed system makes the online monitoring of CPM emissions available and lays a foundation for the control of CPM emitted from industrial sources to further improve air quality.