Determination of 18 photoinitiators in food paper packaging materials by FastPrep-based extraction combined with GC-MS.

Extraction of photoinitiators (PIs) from food paper packages is difficult since they normally hide inside multiple ink layers. A one-step FastPrep-based extraction in combination with GC-MS was developed to simultaneously measure 18 PIs in food paper packaging materials. FastPrep-based extraction enabled direct and efficient release of PIs from raw paperboard in a minute without additional procedures. It was simple, high-throughput, consuming less solvent and not requiring heat or radiation. GC-MS using selected ion monitoring provided identification of PIs with high selectivity. The LODs and LOQs for 18 PIs ranged from 0.060 to 0.614 mg/kg, and 0.197-2.027 mg/kg, respectively. The method was successfully applied for various real samples, and the spiked recoveries using different real sample matrices ranged from 93.3% to 110.1%. The developed method can thus be used for the quality control of PI residues in paper packaging materials of food products.