AgF-Mediated Electrophilic Amination of Alkoxyarylsilanes with Azodicarboxylates
CHEMISTRY-AN ASIAN JOURNAL(2022)
摘要
A facile and efficient AgF-mediated electrophilic amination of alkoxyarylsilanes with azodicarboxylates was developed. The reaction proceeds in green solvent under simple and mild conditions to generate the corresponding aryl hydrazines. AgF acts both as a stoichiometric fluoride source and a reagent for transmetalation to the arylsilver intermediate that eventually reacts with azodicarboxylates to provide aryl hydrazines.
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关键词
amination, alkoxysilane, silver, azodicarboxylate, arylamine
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