Analysis of organic matter conversion behavior and kinetics during thermal hydrolysis of sludge and its anaerobic digestion performance

In thermal hydrolysis (TH) of waste activated sludge (WAS), the material transformation of a specific temperature heating for a set duration is generally examined. However, this study looked at the material changes of TH as the temperature rose (90–210 °C) and the kinetic derivation of soluble chemical oxygen demand (SCOD), protein, and carbohydrate using the Coats-Redfern model. It was found that the proportion of soluble protein and soluble carbohydrate in the organic components and their contents reached the maximum (17.39 and 8.10 g L−1 respectively) at 180 °C. Differently, volatile fatty acid (VFA), amino acids, and ammonia nitrogen increased with the TH temperature and reached a maximum at 210 °C. The fitting equations of non-isothermal dynamics at the medium- and low-temperature stages (90–180 °C) at n = 1, 0.5, and 2 were studied. When n = 1, the activation energies of COD, protein, and carbohydrate were 33.32, 23.34, and 36.15 kJ mol−1, respectively. And the kinetic analysis results were in good agreement with the experimental results (the maximum rate of increase in protein and carbohydrate was at 135–150 °C and 150–180 °C, respectively). Moreover, the pattern of anaerobic digestion performance of WAS was comparable to the trend of protein and carbohydrate in TH, the highest cumulative methane production was 159.68 mL·g−1VS for the TH sludge at 180 °C. This study provided a theoretical foundation for the use of thermal hydrolysis in engineering.