Synthesis of Fluoride-Substituted Layered Perovskites ZnMoO 4 with an Enhanced Photocatalytic Activity.
ACS applied materials & interfaces(2021)
摘要
Oxyfluorides possess considerable attention for their multiple excellent properties, but the conventional high-temperature solid-state syntheses have seen bottlenecks in the synthesis of new compounds. Herein, we report a novel layered oxyfluoride ZnMoO:F, which is prepared by a facile hydrothermal method using ZnF as the fluoride source. The fluoride anions are successfully introduced into the oxygen sublattice, which is confirmed by a combined analysis using XRD, STEM, and TGA techniques. The as-synthesized ZnMoO:F has an absorption edge at around 550 nm, indicating a red shift of to the visible region compared to the oxide counterpart. The layered oxyfluoride exhibits an enhanced photocatalytic active for hydrogen evolution under simulated sunlight (λ > 350 nm), and the activity of ZnMoO:F (651.9 μmol g) was 2 times higher than that of ZnMoO (309.7 μmol g). Further electrochemical analysis has shown that the conduction band position plays a critical role in the high performances of ZnMoO:F. This work sheds new light on the future design and synthesis of novel fluoride-doped materials for photocatalysis applications.
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关键词
ZnMoO4,fluoride-doped oxides,hydrothermal synthesis,layered perovskites,photocatalysis
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