Synthesis of Poly-substituted 2-Hydroxycyclobutanones via Norrish–Yang Photocyclization/1,2-Methyl Migration: Scope and limitations

Tetrahedron Letters(2024)

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Abstract
Poly-substituted 2-hydroxycyclobutanone motifs are core motifs in many biologically important natural products, we recently developed Norrish–Yang photocyclization/1,2-methyl migration as a synthetic strategy for regio/stereoselectively constructing them and profiled the scope and limitations of the proposed strategy in this work.
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Key words
Norrish-Yang cyclization,Cyclobutanone,1,2-methyl migration,DFT study
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