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Separation, speciation, and mechanism of astatine and bismuth extraction from nitric acid into 1-octanol and methyl anthranilate

Evgeny E. Tereshatov,Jonathan D. Burns,Amy L. Vonder Haar,Steven J. Schultz,Lauren A. McIntosh,Gabriel C. Tabacaru,Laura A. McCann,Geoffrey Avila,Andrew Hannaman,Kylie N. Lofton,Mallory A. McCarthy,Bowen Zhang,Michael B. Hall,Sherry J. Yennello

Separation and Purification Technology（2022）

Cited 10|Views19
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Abstract
•Astatine speciation in nitric acid media.•Astatine and bismuth separation using liquid–liquid extraction.•Mathematical modeling of astatine and bismuth behavior.•Mechanism of astatine and bismuth extraction into conventional solvents.•DFT calculations for astatine interactions.
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Key words
Astatine,Bismuth,Speciation,Extraction mechanism
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