NiH-Catalyzed Asymmetric Hydroarylation of N-Acyl Enamines: Practical Access to Chiral Benzylamines
semanticscholar(2020)
Abstract
The enantio- and regioselective reductive hydroarylation of N-acyl enamines has been achieved with a NiH catalyst and a chiral bis-imidazoline ligand. A broad range of structurally diverse, enantioenriched benzylamines, a moiety found in many pharmacologically active molecules, have been synthesized efficiently under mild, operationally simple reaction conditions.
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