Thermal barrier coatings with high-entropy oxide as a top coat

A pyrochlore-structured La-2(Zr0.2Ce0.2Hf0.2Sn0.2Ti0.2)(2)O-7 high-entropy oxide was designed and synthesized, and its properties were tested. Traditional two-layer structured thermal barrier coatings (TBCs) with a La-2(Z-r(0.2)Ce(0.2)Hf(0.2)Sn(0.2)Ti(0.2))(2)O-7 top-coat were prepared by plasma spraying. A phase-pure defective-fluorite high entropy-oxide top coat was thus obtained. The results confirmed the possibility of synthesizing pyrochlorestructured La-2(Zr0.2Ce0.2Hf0.2Sn0.2Ti0.2)(2)O-7. The material exhibited a low thermal conductivity, which increased with increasing temperature. The coefficient of thermal expansion (CTE) of La-2(Z-r(0.2)Ce(0.2)Sn(0.2)Hf(0.2)Ti(0.2))(2)O-7 ranged from 7.55 x 10(-6) degrees C- 1 to 8.63 x 10(-6) degrees C-1 for the corresponding range of room temperature to 1000 degrees C. After 10 thermal cycles at 1050 degrees C, the La-2(Zr0.2Ce0.2Hf0.2Sn0.2Ti0.2)(2)O-7 top coat spalled in the TBC. Spallation did not occur at the interface between the bond coat and the thermally grown oxide layer, while it is in the top coat near the bond coat. Owing to the low fracture toughness and low CTE, the thermal cycling lifetime of TBCs with the La-2(Zr0.2Ce0.2Hf0.2Sn0.2Ti0.2)(2)O-7 top coat was short.