A General Carbonyl Alkylative Amination Process for Tertiary Amine Synthesis
semanticscholar(2019)
摘要
We report a practical
and general solution to this long-standing synthetic challenge can be
accomplished by addition of alkyl radicals to all alkyl-iminium ions. The
process is mediated by the action of visible light and a simple silane reducing
agent, establishing a chain process that permits the combination of an
extremely wide range of aldehydes and secondary amines with alkyl halides.
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